Jill Scott Scores First #1 on Billboard 200

Bon Iver debuts at #2, followed by Adele at #3 and 'Weird Al' Yankovic at #9.

R&B singer Jill Scott will notch her first #1 album next week when her fourth effort, Light of the Sun, crashes the top of the Billboard 200 chart thanks to sales of 135,000 copies, according to figures provided by Nielsen SoundScan.

That was more than enough to hold off the charge from another chart-topping newbie, sensitive Wisconsin folkie Bon Iver (a.k.a. Justin Vernon), whose self-titled second collection of pastoral Auto-Tuned hymns hits #2 after selling 104,000 copies.

The pair leads a parade of new faces, which include country singer Justin Moore at #5 with Outlaws Like Me (65,000), Pitbull, whose Planet Pit lands at #7 (55,000), and perennial chart-crashing joke man “Weird Al” Yankovic , who yuks his way to #9 with Alpocalypse (44,000).

The rest of the top 10: Adele, 21 (#3, 101,000); Jackie Evancho, Dream With Me (#4, 77,000); Bad Meets Evil, Hell: The Sequel (#6, 63,000); Lady Gaga, Born This Way (#8, 49,000); and Jason Aldean, My Kinda Party (#10, 40,000).

Speaking of parties, all-night disco rockers LMFAO wiggle in just outside the top 10 with their second effort, Sorry for Party Rocking, which hits #12 (27,000), while soul singer Ledisi takes a 10-spot tumble in week two with Pieces of Me, which falls to #18 (20,000). Without a smash hit like “Fireflies,” fans seemed to flee Owl City‘s latest, All Things Bright and Beautiful , which plummets 26 spots in week two to #32, as sales drop 73 percent to 13,000.

Pop punk veterans Simple Plan rolled into the #52 slot with Get Your Heart On! (9,000).

Over on the iTunes charts, it’s a different story, as Bon Iver rules the album tally, followed by Adele, Scott, the Eminem and Royce Da 5’9″ collabo Bad Meets Evil, Pitbull, Moore, Mumford & Sons’ Sigh No More, LMFAO, Matt Nathanson’s Modern Love and a Frank Sinatra greatest hits collection.

Katy Perry was the queen of the iTunes singles chart thanks to “Last Friday Night (T.G.I.F.),” which beat out Maroon 5′s “Moves Like Jagger” collaboration with Christina Aguilera on “The Voice,” then LMFAO’s “Party Rock Anthem,” Pitbull’s “Give Me Everything,” Nicki Minaj’s “Super Bass,” Adele’s “Rolling in the Deep,” Lady Gaga’s “The Edge of Glory,” Hot Chelle Rae’s “Tonight Tonight,” Lil Wayne’s “How to Love” and Blake Shelton’s “Honey Bee.”

Expect more shake-ups at the top next week when Beyoncé’s 4 charts, along with new ones from Selena Gomez, former “American Idol” winner David Cook, Big Sean, Curren$y and, yes, the reunited Limp Bizkit.

I'm so fancy.